Organic Chemistry

11

Sunil Kumar ·2009-02-19 07:02:41

Have a look.

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11

Sunil Kumar ·2009-02-21 01:01:12

bas ravi tune kar diya mazak faaltu main.......
joke mat maar jawab de........

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1

Ravikant Mishra ·2009-02-21 00:59:38

what is iodoform test????

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1

Ravikant Mishra ·2009-02-21 00:55:09

the compound is very stable there fore it doesn't give the iodoform test

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11

Sunil Kumar ·2009-02-19 07:31:46

Ok...

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1

vector ·2009-02-19 07:31:03

i ve just posted 4 or 5 que try them

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11

Sunil Kumar ·2009-02-19 07:27:28

I didn't said U r wrong.
I just wanted to show that there is enolate ion formation in the mechanism....

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vector ·2009-02-19 07:24:11

that s wat i had posted

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11

Sunil Kumar ·2009-02-19 07:22:28

For the question u gave i'm not much convinced by the fact that due to enol formation poses a problem for reaction cause enolate ion are always in equilibrium with keto group and their concentration is larger in solution only when there is Î² diketones or any carbonyl compound in which there is resonance stabilisation or intramolecular H-bonding.

So I also think the main factor should be Stearic hindrance.....

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1

vector ·2009-02-19 07:16:54

but do u think it has sum thing to do wid rate n feasiblity of rxn

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11

Sunil Kumar ·2009-02-19 07:11:28

There is a transition of Carbonyl group and the enolate ion at every stage....

So the red boxes compounds in the diagram are always in equilibrium with enolate ion.
So u can't deny the fact that there is enolate ion in the reaction.