Thanks aditya for correction.
Resistance increases linearly with temp, ie why the formula i used is valid only incase of linear dependance.
However for kinetics the rate is exponentially dependent on temp.
10 Answers
rishabh
·2012-03-17 11:05:59
2) let the rate constant of both rxns at 25 deg. be K
let temp. coeff of rxn. 1 = r then coeff of 2nd rxn = 2.5 r
then by def. of temp. coeff. rate constants will become r^7 * k and (2.5r)^7 * k
hence ans. = (2.5)^7
Swaraj Dalmia
·2012-03-17 11:09:55
3)(A)
In reactions no. of equivalents remain the same.
3/(x+8)=5/(x+35.5)
x=33.25(ans)
rishabh
·2012-03-17 11:14:01
3) MOn/2 ---> M Cln
=> 3M + 8n = 5M+(35.5)n
=> solving we get M/n = 33.25 (A)
Swaraj Dalmia
·2012-03-17 11:18:18
2)Let temp. coefficient be x.
Temp. diff=θ=71
r1final=r1(1+x*θ)
r2final=r2(1+2.5x*θ)
r2/r1=(1+2.5x*71)/(1+x*71)≈2.5(ans)
Swaraj Dalmia
·2012-03-18 10:09:11
Vivek @ Born this Way
·2012-03-19 01:56:19
So what is the answer for second?
THanks all for the rest.
rishabh
·2012-03-19 02:43:14
has to be slightly greater than (2.5)^7 as i already posted.
since i've approximated 96 degrees to 95 degrees.