DOUBTS!!!

NEWLY ADDED QUESTIONS unsolved questions are underlined.
1.for what value of k the system of linear equations x+2y+x=1;x+3y+4z=k;x+5y+10z=k2 has solution?find the solution in each case. [roorkee 97] SOLVED
2.true/false(plz give reasoning as well):
i.graphite is a better lubricant on moon than on earthans:F SOLVED
ii.CCl4 is inflammable. ans:F SOLVED
3.complete the reaction: SOLVED
Zn+dil HNO3→
Will add more later.

40 Answers

13
Avik ·

2) i- Yeah arka, Yahaan bhi True supported hai-

http://books.google.co.in/books?id=0-cDAAAAMBAJ&pg=PA818&lpg=PA818&dq=graphite+is+a+better+lubricant+on+moon&source=bl&ots=P_r7JasXWo&sig=sCSnmaONTVN9HAM_04v3yIBcL4c&hl=en&ei=Vay0S57lD5GtrAejqvxB&sa=X&oi=book_result&ct=result&resnum=6&ved=0CCAQ6AEwBQ#v=onepage&q=graphite%20is%20a%20better%20lubricant%20on%20moon&f=false

39
Pritish Chakraborty ·

8. a), b), d) if the question is asking for the factors upon which oxidation potential depends.

a), d) if the question is asking for those factors which support it.

1
" ____________ ·

9 .divide by x^2

put x± 1/x = t

accordingly

u get ansr[1]

1
Arka Halder ·

10. jee 09:multi correct SOLVED
the compounds formed upon combustion of Na in excess air are:
a)Na2O2 b)Na2O c)NaO2 d)NaOH
ans given a,b,'d'.shudnt it b only a,b?

11. SOLVED

1
Arka Halder ·

q 5.)proceeding as avinav did,

exactly what pritish stated.
that's what confused me yesterday.
got the answer now[1]
ques 2(i),7,10,11 still unsolved.

1
tapan ·

11. none.
am getting RHL=0 and LHL=sin 1,so limit does not exist.
please verify.

1
Avinav Prakash ·

10.>

NaOH is obtained when it reacts with moist air

while other 2 obtained with dry air

1
rickde ·

@ Arka

u saw the solutions from any institution na....dont believe in them

IIT themselves released the solutions to IITJEE 2009....get it at the JEE 2010 site previous papers link

dil kush ho jayega....................[4]

ans is A,B

13
Avik ·

100% on agreement with rick.
Get the 07,08,09 pprs & sol.n frm the JEE websites itself...most reliable & accurate :)

11) Yes, should be d).

1
rickde ·

r u sure of 2(i)
in my solutions it is given true

reason is that the gravity on moon is less ...so friction will be less n graphite will be more slippery

confirmed form my sirs....

1
Avinav Prakash ·

5.) USING KINETIC THEORY OF GASES

V=√3RTM

MOW MULTIPLY h/λ ON BOTH SIDES

SO

λ IS α √MT

SUSTITTUE THE VALUS TO GET (A) AS THE ANS=1.633

1
Arka Halder ·

yeah me too was confused.
graphite q was taken from fiitjee past year iit questions.
Na ques was taken from the solution booklet of jee 09 by an institute 'prerena classes'got from school on farewell that 2 for free[3].
anyway thanks everyone for the verification.was really doubtful regarding these.

1
Arka Halder ·

plz try q 7.its still unsolved.

1
Arka Halder ·

SOLVED
please give reason or show working of ur method.
12. multi correct:

13.When mercuric iodide id added to aq KI solution,then:
a)freezing pt is raised
b)freezing pt is lowered
c)freezing pt doesnt change
d)boiling pt doesnt change
14.What is the gas evolved when PbO2 reacts with conc HNO3?

1
rickde ·

freezing point is raised....dis is due to formation [HgI4] - complex which results in -ve vant hoff factor.....

too lazy to show u the calculations........u can do it urself

29
govind ·

PbO2 on reaction with HNO3 produces both NO2 and O2

1
raja ·

For the 12th one, ans is a) 4.

21
eragon24 _Retired ·

12) hint:: every perfect odd square is of form 8k+1

after tat use some property of deters...

i think u shud get it then.

1
Arka Halder ·

thanks 4 d verification,govind.it was a single option correct q from fiitjee and the ans was given as O2 when both O2 and NO2 were given.
raja 12 is multi correct,ans are A,C.
madhu ans for 7 is given on #19 of this thread.its a bizarre ans,am gettin nowhere near it[3]from ADG,hopefully not wrong ans

1
Arka Halder ·

A few final doubts.plz reply with reasoning
1.A solution of Na in liquid NH3 at -33°C conducts electricity.On cooling the conductivity of this solution _______.
ans:decreases

1
Arka Halder ·

thanks a lot avik and eragon[1].
few more:plz tell the method to proceed,just not the ans
5.ratio of de broglie wavelengths of molecules of H2 and He at 27 and 127°C respectively is:
a)1.633 b)0.612 c)1.265 d)0.79 ans:A
6. SOLVED
shouldnt answer be d?
answers to T/F were both false saket.

39
Pritish Chakraborty ·

Solve Q1 by determinant method?

1
Arka Halder ·

as i calculated, Δ=0 as it comes out to be.
but what after that?

21
amit sahoo ·

2)
i)true- as there will be lesser friction on moon......so function of lubricants will be easier.

ii)false......reason is that actually ccl4 is used in fire extinguishers.[11]

39
Pritish Chakraborty ·

arka if A is a singular matrix I think it has no solution...I don't remember. Will consult theory and tell you.

39
Pritish Chakraborty ·

And in the metre bridge question, the null point which is closest to the midpoint of the scale will give most accurate reading. This is given in any lab manual, they show you how by error calculations that X = x/2 is the best spot and anything near it will give accurate reading. So the ans should be B.

1
Arka Halder ·

thanks pritish.
you r right regarding metre bridge question.
saket,will verify ur answers 2moro.
regarding q 1,if Δ=0,there can still be a case of infinite solutions,cant it be pritish.
havent solved any of that type so need solution of this sum.

1
Arka Halder ·

plz answer 1 and 3.

13
Avik ·

3) came last yr i think in match the columns, dunno exactly.

Anyways, this is an exceptional case when Zn reacts with dil. HNO3,

* 2HNO3 ----> H2O + N2O + 4O (gives N2O instead of NO)
* Zn + O ----> ZnO
* ZnO + 2HNO3 -----> Zn(NO3)2 + H2O

Now Multiply/Add/Cancel out....u'll get the reaction.

21
eragon24 _Retired ·

1st

here since D=0

so for having infinite soln u will hav D1= D2= D3=0

D1 D2 D3 denote the standard notation for determinants

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