25-02-09 Biggie in organic

This is the biggest question n organic till date in the forum...

Enjoy!!
[3]

Edit: ( after AgNH3 and H+) after S ... 1 eq of red P HI is added

110 Answers

21
tapanmast Vora ·

(CHO-CHO) = R

39
Dr.House ·

kya hain woh? konsa waale ka?

sorry maine upar wala double bond R samja, sorry

itne gusse kyun hote hon? sorry again

21
tapanmast Vora ·

NAHI NAHI JUS MAZAK DUDE!!!

33
Abhishek Priyam ·

J K L R are right..

21
tapanmast Vora ·

not sure ? : Is S = CH2OH-COONa

33
Abhishek Priyam ·

:(

sodium alcohol reduces..so how -COONa

21
tapanmast Vora ·

oh k k... iska matlab CH2OH-CHO......

hmmm. so the next prod on Tollen's test gives CH2OH-COOH rite....

then HVZ to give CHBrOH-COOH

33
Abhishek Priyam ·

before HVZ and (T)
red P HI is also addded(1eq)

33
Abhishek Priyam ·

and in HVZ Br2 is in excess so BrCH2-COBr will be formed

21
tapanmast Vora ·

oh yah!!! dat p/HI wud reduce -OH to H and then HVZ... true true....

lemme try ahead... aage lagta hai kuch Claisen hone wala hai....

BUT I had a DBT DUDE : In HVZ if its excess then first all the α-H are substituted by Br, then only wud the H of carboxylic acid be replaced,........ WAT SAY?

21
tapanmast Vora ·

SO MY ANS FOR Z WUD (Br)3C-COOBr

21
tapanmast Vora ·

U = CH3COOC2H5

fir CLAISEn KAKA....

matlab

V = CH3COCH2COOC2H5.....

fir firse CLAISEN....

21
tapanmast Vora ·

21
tapanmast Vora ·

(CH3)-(CH2)-COOH = Y

33
Abhishek Priyam ·

rest U V Y Z O P Q are correct..

u are right about excess HVZ...

33
Abhishek Priyam ·

21
tapanmast Vora ·

HEY!

Y is the product formed after arndt eistert reaction of CH3-COOH then shud it not b propanoic acid as i sadi?? [7]

33
Abhishek Priyam ·

Oh.. in question thers Ag2O moist also i din sae that... yeah Y is also right...

33
Abhishek Priyam ·

21
tapanmast Vora ·

yah I know I havnt touchd upon the product I.... still thinkin [12]

It feels like pentanoic acid or sumthin but the reaction sequence doesnt suite it...

lemme [12]

21
tapanmast Vora ·

dude,
wats the eq. of H2 used in converting M to N ?? [7]

33
Abhishek Priyam ·

33
Abhishek Priyam ·

M->N excess H2/Ni

33
Abhishek Priyam ·

21
tapanmast Vora ·

This will be the intermediate after intermol. claisen enroute frm V to W :
CH3-CO-CH2-CO-CH2-CO-OC2H5

Then on reaction with dat dibromoo comp. ??? mayb cyclisation (WILD GUESS = BLUFF) [3]

33
Abhishek Priyam ·

~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

These are the answers done here.. rest are not solved...

~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
W X and I M N...

so try these

33
Abhishek Priyam ·

W is wrong... :(

21
tapanmast Vora ·

No DUDE I havnt givn my ans for W....

Wat i hav shown is da likely intermediate via intermol. claisen is all wat i hav said

33
Abhishek Priyam ·

kk...

21
tapanmast Vora ·

priyam : is I pentanoic/butanoic acid or wat?

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