Bonding7

Which has highest MP?
NaCl
KCl
MgO
BaO

How?

15 Answers

24
eureka123 ·

Get answer through fajan's rule

1
D Queen ·

@ eureka

I know that but how will i compare Mgo to NaCl??Using charge density??But i dont know how to??

24
eureka123 ·

Na^+,K^+,Mg^{2+},Ba^{2+}

Now higher the charge greater is covalency=> \ Melting \ point \ order \ :Na^+,K^+>Mg^{2+},Ba^{2+}

Now if charge same..smaller the size greater the covalency,

\begin{matrix} We \ know \ size :K^+ >Na^+\\ => Covalent \ character \ : Na^+>K^+ \\ => Melting \ point \ :K+>Na^+ \\ => Max. \ melting \ point =KCl \end{matrix}

I hope its clear now...

106
Asish Mahapatra ·

But eure, MgO has max MP i think..

Check up the values

24
eureka123 ·

I dont have the values...jsut did it by logic...anyways i will check now..

24
eureka123 ·

Ya..the values show opp trend...dont know why[7][7]

1
Unicorn--- Extinct!! ·

I think it has something to do with packing of the molecules in a lattice.

1
abhishek upadhyay ·

yes iota is right

1
sakshi pandey pandey ·

isnt it any application of diagonal relationship bcos li is more covalent than Na & its comparable to Mg .....

1
D Queen ·

Yeah answer is also given as MgO but acc to Fajan it should be KCl..Now why??

1
D Queen ·

Hi

24
eureka123 ·

thats teh real problem....i dont see anything wrong in my working....so how are we going to do in exam ???

1
D Queen ·

We have to learn some of the things but its gud if anyone can explain this to us

24
eureka123 ·

we cant learn MP,BP and oher things of million compounds....there must be some logic...out of thousand other logics in inorganic

1
Unicorn--- Extinct!! ·

None of you think that it is related to packing of molecules?

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