1
aieeee
·2009-09-17 11:00:49
H2SO4 + HI → I2 + SO2 + H2O
K2Cr2O7 + HCl → KCl + Cr2O3 + Cl2
CaOCl2 + NaI + HCl → NaCl + CaI2 + Cl2 + H2O
24
eureka123
·2009-09-17 11:06:17
tell me how did u write the products ??
this is one thing I am very weak in....can u explain how did u do that ?
1
aieeee
·2009-09-17 11:18:20
see , 1st one is a standard redox reaction in which H2SO4 ,being a strong oxidising agent oxidises I- to I2 and itself gets reduced to SO2.
2ND ONE : same as the 1st one . here K2Cr2O7 acts as a strong oxidising agent carrying out the redox reaction.
3rd one is a bit complicated. in it,i first did the reaction of HCl and CaOCl2 forming CaCl2 and HOCl. now reaction of the products wid NaI , forming the above products.
24
eureka123
·2009-09-17 11:24:46
3rd
but why didnt CaOCL2 and NaI or NaI and HCl react in first step ???
3
msp
·2009-09-17 11:31:13
watever it may be eure the most stable product will only be formed.
24
eureka123
·2009-09-17 11:33:04
hmmm
so if CaOCL2 and NaI react what will be intermediate product ??
or if NaI and HCl react?
1
aieeee
·2009-09-17 23:36:15
dude,first of all CaOCl2 and NaI will not react at all in the anhydrous state. because fr this reaction 2 take place , H2O needs 2 be der to first dissisiate CaOCl2 into Cl2 and Ca(OH)2 and the products ( especially Cl2 reacts wid NaI ).
and fr the combination of NaI and HCl , de'll form NaCl and HI . now, HI reacts wid CaOCl2 to frm the remaining products i.e. CaI2 + Cl2 + H2O