29/10/2009

If D(t) and D(o) are the theoretical and observed vapour densities at a definite temperature and @ be the degree of dissociation of a substance. Then, find @ in terms of D(o),D(t) and n (number of moles of products formed from 1 mole reactant).

2 Answers

1
aieeee ·

I think ders a formula for this :

@ = (D(t) - D(o)) / [(n - 1)D(o) ]

1357
Manish Shankar ·

An→nA
1 0
1-a na

Let the molecular mass of An=M
And at equilibrium, M'
then we have, at equilibrium
(1-a)M+na(M/n)=(1+na-a)M'

M-M'=a(n-1)M'
a=M-M'(n-1)M'
a=D(t)-D(o)(n-1)D(o) VD=M/2

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