Solutions

The molal lowering of vapour pressure of a liquid is 1.008 mm Hg at 25oC in a very dilute solution containing non volatile solute.The vapour pressure of the liquid at 25oC
is 'A'x10 mm Hg.The value of 'A' is...... [ Integer type ]

Note: Molecular weight of liquid =18.

Steps plz...

4 Answers

262
Aditya Bhutra ·

is the answer 5?

1
chessenthus ·

Hello Aditya,

Sorry, the answer given is 6.

21
Swaraj Dalmia ·

Molal lowering of V.P.=1.008
i.e. if son. is 1 molal conc. then ∂V.P.=1.008
For 1 molar conc:
No of moles of solutes=1.
Wt of soln=1000g
therefore no. of moles of solute=1000/18.

Relative decrease of V.P.=mole fraction of solute
∂V.P./V.P.=1/(1000/18)
V.P.=1.008(1000)/18=56.
A=5.6

Nearest integer=6(if we do not approximate using very dil. son. the ans is closer to 6)

1
blueivy ·

@Swalraj Sharma, you have done a mistake, it would be
V.P.=1/(1000/18 + 1)
but still the answer comes to be 5.695

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