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1. The ionic radii of Ca2+ and Na+ ions are about the same yet calcium ions are more hydrated than sodium ions. Suggest an explanation for this.

7 Answers

1
lubu ·

The group 2 ions have more hydration energy than gruop 1 ions (may be 5 times).This is due to smaller size. So Ca+2 more hydrated than Na+1.

1
Manmay kumar Mohanty ·

hydration energy of Na+ is - 435 KJ mol-1 while that of Ca +2 is - 1577 KJ /mol. so calcium ions are more hydrated than sodium ions [1]

3
rocky ·

CALCULATE E/Z FOR THE TWO......AND SMALLER ONE HAS LOWER VALUE FOR E/Z ...SO IT IS MORE EASILY HYDRATED

3
rocky ·

@MANMAY HERE REASON IS ASKED....IT IS ALREADY KNOWN THAT calcium ions are more hydrated than sodium ions

29
govind ·

Ca2+ has more charge density than Na+ ..that's the reason why calcium ions are more hydrated than sodium ions....

1
Manasi Deshpande ·

if u c thru z/e ratio then more is itzz value so less is the size........since size is less so d ion has higher charge density n its attraction force gets comparitively higher than larger size atoms so all together it aatracts more H2O molecules forming BIGGER HYDRATED SIZE.........

1
Arka Halder ·

ya agree with govind..
both size and the charge has to be considered.

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