Properties and uses of important polymers

Here is some info regarding polymers from wikipedia.
1.Natural rubber:
Natural rubber is an elastomer (an elastic hydrocarbon polymer) that was originally derived from a milky colloidal suspension, or latex, found in the sap of some plants. The purified form of natural rubber is the chemical polyisoprene, which can also be produced synthetically. Natural rubber is used extensively in many applications and products, as is synthetic rubber.
Rubber exhibits unique physical and chemical properties. Rubber's stress-strain behavior exhibits the Mullins effect, the Payne effect, and is often modeled as hyperelastic. Rubber strain crystallizes.
Owing to the presence of a double bond in each repeat unit, natural rubber is sensitive to ozone cracking.
Natural rubber is often vulcanized, a process by which the rubber is heated and sulfur, peroxide or bisphenol are added to improve resilience and elasticity, and to prevent it from perishing. Vulcanization greatly improved the durability and utility of rubber from the 1830s on.[citation needed] The development of vulcanization is most closely associated with Charles Goodyear in 1839. Carbon black is often used as an additive to rubber to improve its strength, especially in vehicle tires.
2.Cellulose:
Cellulose is an organic compound with the formula (C6H10O5)n, a polysaccharide consisting of a linear chain of several hundred to over ten thousand β(1→4) linked D-glucose units.
Cellulose is soluble in cupriethylenediamine (CED), cadmiumethylenediamine (Cadoxen), N-methylmorpholine N-oxide and lithium chloride / dimethylformamide. This is used in the production of regenerated celluloses (as viscose and cellophane) from dissolving pulp.
Cellulose has no taste, is odourless, is hydrophilic, is insoluble in water and most organic solvents, is chiral and is biodegradable. It can be broken down chemically into its glucose units by treating it with concentrated acids at high temperature.
3.Nylon:
Nylon is a generic designation for a family of synthetic polymers known generically as polyamides and first produced on February 28, 1935 by Wallace Carothers at DuPont. Nylon is one of the most commonly used polymers.
Nylon 6,6 can have multiple parallel strands aligned with their neighboring peptide bonds at coordinated separations of exactly 6 and 4 carbons for considerable lengths, so the carbonyl oxygens and amide hydrogens can line up to form interchain hydrogen bonds repeatedly, without interruption. Nylon 5,10 can have coordinated runs of 5 and 8 carbons. Thus parallel (but not antiparallel) strands can participate in extended, unbroken, multi-chain β-pleated sheets, a strong and tough supermolecular structure similar to that found in natural silk fibroin and the β-keratins in feathers. (Proteins have only an amino acid α-carbon separating sequential -CO-NH- groups.) Nylon 6 will form uninterrupted H-bonded sheets with mixed directionalities, but the β-sheet wrinkling is somewhat different. The three-dimensional disposition of each alkane hydrocarbon chain depends on rotations about the 109.47° tetrahedral bonds of singly-bonded carbon atoms.
4.Teflon:
In chemistry, polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene which finds numerous applications. PTFE is most well known by the DuPont brand name Teflon.
PTFE is a white solid at room temperature, with a density of about 2.2 g/cm3. According to DuPont its melting point is 327 °C (621 °F), but its properties degrade above 260 °C (500 °F). PTFE gains its properties from the aggregate effect of carbon-fluorine bonds, as do all fluorocarbons.
The coefficient of friction of plastics is usually measured against polished steel.PTFE's coefficient of friction is 0.1 or less,which is the second lowest of any known solid material (diamond-like carbon being the first). PTFE's resistance to van der Waals forces means that it is the only known surface to which a gecko cannot stick.
5.PVC:
Polyvinyl chloride, (IUPAC Poly(chloroethanediyl)) commonly abbreviated PVC, is a thermoplastic polymer. It is a vinyl polymer constructed of repeating vinyl groups (ethenyls) having one of their hydrogens replaced with a chloride group.
It is used in pipes,electronic accessories and clothing.

1 Answers

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Pritish Chakraborty ·

1. Vulcanization of rubber basically adds S-S bonds, or disulphide bridging to rubber which makes it more durable.

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