Organic General problems

I Am having a few simple problems....

1)In a book dat i have been reading it is said -"Dipole moment of trans-dichloroethylene is zero while cis-dichloroethylene has a definite dipole moment"...WHY?
2) Is there any technique or method to solve the following problems--
(a)How many chain isomers can be obtained from the alkane C6H14 ?
(b) The maximum number of an alkene with molecular formula C4H8 is?
(c) The total number of isomers for the compounds of the formula C4H8O is ?

Lastly What is α-hydrogen?

8 Answers

62
Lokesh Verma ·

1)In a book dat i have been reading it is said -"Dipole moment of trans-dichloroethylene is zero while cis-dichloroethylene has a definite dipole moment"...WHY?

This is a very good question.

See about the center, the direction of dipole is not cancelled. The component in the cis conformer remains un-removed. See that image

62
Lokesh Verma ·

62
Lokesh Verma ·

2) Is there any technique or method to solve the following problems--
(a)How many chain isomers can be obtained from the alkane C6H14 ?
(b) The maximum number of an alkene with molecular formula C4H8 is?
(c) The total number of isomers for the compounds of the formula C4H8O is ?

There is no technique or formula.. you will see some formulas here and there but they are not reliable. This will come directly after a couple of problems that you solve. :)

62
Lokesh Verma ·

What is α-hydrogen?

Source: Wikipedia

The alpha carbon in organic chemistry refers to the first carbon that attaches to a functional group (the carbon is attached at the first, or alpha, position).[1] By extension, the second carbon is the beta carbon,[2] and so on. This nomenclature can also be applied to the hydrogen atoms attached to the carbons. A hydrogen attached to an alpha carbon is called an "alpha-hydrogen" (α-hydrogen), a hydrogen on the beta-carbon is a beta-hydrogen, and so on.

1
Arpan Banerjee ·

1) For the explanation to the 1st question...how come the dipole moment of trans-2,3-Dichloropentene-2 is not zero?

3) For the explanation to ques 3.....is the Carbon atom of the methyl group shown in the diagram also a α-Carbon?

1
Arpan Banerjee ·

pls reply

62
Lokesh Verma ·

]
1) For the explanation to the 1st question...how come the dipole moment of trans-2,3-Dichloropentene-2 is not zero?

I did not understand what you mean.. we had to show that it gets cancelled. ANd it does indeed!

62
Lokesh Verma ·

3) For the explanation to ques 3.....is the Carbon atom of the methyl group shown in the diagram also a α-Carbon?

Yes that is also an alpha carbon.

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