isomerism

pls give structure of all isomers of the complex

[ Co (NH3)5 (NO2) ] (NO3)

2 Answers

1
sakshi pandey pandey ·

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39
Pritish Chakraborty ·

Ionisation Isomers-:
[Co (NH3)5 (NO2) ]NO3 and
[Co (NH3)5 (NO3) ]NO2

Linkage Isomers-:
[Co (NH3)5 (NO2) ]NO3 and
[Co (NH3)5 (ONO) ]NO3
due to ambidentate ligand nitro/nitrito.

Complexes of this type [MA5B] do not show geometrical isomerism or cis-trans isomerism because positions of ligands wrt metal atom are equivalent..

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