Why BCl[ss]3[/ss] does not form dimer unlike AlCl[ss]3[/ss]?

Why BCl3 does not form dimer unlike AlCl3?

6 Answers

1
aieeee ·

In fact, a B-Cl-B bond may occur in BCl3 as it does in AlCl3, but due to the small size of B, it is not possible.
another reason might be the fulfilled valency of B .

1
decoder ·

because B has a small size which cannot accomodate 4 large sized Cl- ion.

1
champ ·

Thank You
:-)

3
msp ·

but BH3 can form dimer as u know.

24
eureka123 ·

@sankara..
H atoms are small compared to Cl so they can be accomodated ..whereas Cl not

3
msp ·

yeah i know,just give but the actual reason is different that is the bonding is different from other compounds,in BH3 a special type of bonding is there,this type of bonding is in Al(CH3)3 these compounds have a common name called cluster compounds,so the 3c-2e bond doesnt depend on the size of the hydrogen.

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