alcohol3

give reasons

4 Answers

39
Pritish Chakraborty ·

Diazotization cum pinacol rearrangement..

You can see the rotation of those groups more easily in sawhorse projection. In case rotation across the bond carbon-carbon bond is HINDERED, ONLY migratory aptitude decides which group will replace the leaving group, as compound cannot rotate freely for a certain group to obtain anti-conformation wrt leaving group. If no hindrance, anti conformation is ALWAYS preferred.

3
rocky ·

but A is given as answer [5][5]

39
Pritish Chakraborty ·

Koi mechanism diya hua hai? Unless we can find anything wrong in how I've worked out it, I'm going with B...

3
rocky ·

nahi bhaiya

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