Assertion n Reason on Feb 12th

1. Statement-I : Benzoic acid is a weaker acid than formic acid
Statement-II : Phenyl group when attached to carbonyl group becomes electron donating.

2. Statement-I : Pb4+ can be reduced rasily to Pb2+
Statement-II : Pb2+ is paramagnetic

3. Statement-I : HNO3 is stronger acid than HNO2.
Statement-II : In HNO3 there are two N – O bonds whereas in HNO2, there is only one N – O bond

4. Statement-I : Zn2+ is diamagnetic.
Statement-II : The electrons are lost from 4s – orbital to form Zn2+.

5. Statement-I : Nitration of anilline can be done by protecting – NH2 group through acetylation.
Statement-II : Acetylation of aniline results in the increase of electron density in the benzene ring.

10 Answers

1
abcd ·

1: reason is false
3. reason is false
4. both are true but reason dosent explain the assertion
2. same as 4
5: same as 4

1
soumyadeep sanyal ·

1)both true
2)reason false
3)both true(electron withdrawing effect of two oxygen stabilises the conjugate base)
5)reason false

4
UTTARA ·

1) D

2) B

3) C

4) B

5) B

1
Avinav Prakash ·

1.b
2.b
3.c
4.b
5.b

11
Gone.. ·

1,4,5 - b

29
govind ·

1→ B
2→ C (Pb2+ is dimagnetic)
3→ C
4→ B
5→ C

4
UTTARA ·

@Govind : Pb2+ is paramag no???

Can u also explain 5 (C)

29
govind ·



So acetylation of aniline electron density decreases on benzene ring ..

Pb belongs to grp 14 carbon grp..config ns2np2 if 2 electrons are lost from p the cation becomes dimagnetic...

4
UTTARA ·

Ya Thanks

1
ronak agarwal ·

1-->b
2-->c
3-->c
4-->b
5-->c

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