contradictory answers

BT says a) wheras arihant says b)

16 Answers

1
pranav ·

probabably......(a) .....as it is a strong base,,,,,,,,,,and a side product wud be (b),,,,,vaise weres pritish ?? :)

1
abhishek sahoo ·

mujhe b lagta hai

29
govind ·

It's a strong base as well as strong nucleophile...so there are good chances of substitution through SN2 mechanism also...so answer can be B...

39
Pritish Chakraborty ·

Defining factor : Temperature.
Both are possible.

24
eureka123 ·

any final conclusion ???

1
JOHNCENA IS BACK ·

@all.........hey these days it seems all are having fun lollllllll

yaar wats the debate here???????

clearly.....(b) is the right answer[1][for this question,in fact]

these BT people suck!!!!

24
eureka123 ·

thanks aieeee [1]

1
Philip Calvert ·

I logged in specially to agree with AISSCE
yes BT Sucks

1
aieeee ·

hey guys, lots of confusion. AISSCE and aieeee are two different guys altogether.

cn we plz hv the reasoning here ? nothing specific but just a simple query !

24
eureka123 ·

@aieeee ...anything left ??u said b naa ??

1
JOHNCENA IS BACK ·

OOOHHH.......SORRY NEVER KNEW THAT[1]BUT BY THE WAY WAT IS ORIGINAL????

39
Pritish Chakraborty ·

LOL kya baat hai... an impostor :P

1
JOHNCENA IS BACK ·

@pritish i din get u!!!

1
aieeee ·

hey , pritish, nothing like dat. we hv the same posters, thats yet. we two are two different guys.
and @ AISSCE , sorry fr the controversial statement, i hv deleted it.

@ eure, i just wanted to know the logic behind the answers given. anyways, here goes my logic.

There are two ways possible :

i) acidic hydrogen from phenol goes to the ethoxide ion and ethanol is formed leaving phenoxide ion as the nucleophile.
as phenoxide ion is though strong , but hindered base hs the possibility of elimination.

ii) ethoxide ion directly attacks the halide. in this case the nucleophile is ethoxide ion , which is strong and non-hindered. thus, the possibility of elimination is negligible.

tus the mechanism goes through 2nd method and diethyl ether is formed.

29
govind ·

Since the medium is ethanol so there will be some ethoxide ion left even after extracting the proton from phenol..so in that case there will be competition b/w ethoxide and phenoxide ion..since ethoxide is a better nucleophile so option B will be correct....that's what i think...

@Aieee...just a li'l correction...diethyl ether will be formed as product and not ethyl ester

24
eureka123 ·

thanks all.....

and thanks aieeee for that explaiantion

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