dbts

Q1

Q2/3

8 Answers

1
Manmay kumar Mohanty ·

Q2) since pressure is low so pressure correction n2aV2 can be neglected.

So equation becomes, P(V - nb) = nRT Dividing by nRT througout we get,

PVnRT - PnbnRT = 1,

Z - bRTp = 1,

Z = 1 + bRTp ................which is option(b)

(not sure of the ans.)

106
Asish Mahapatra ·

i think since pressure is low, then volume is high.. so volume correction will be neglected...

??

29
govind ·

Ans 3 A..see when NaoH is added buffer is formed at point A ..then at point B first equivalence..then at C again buffer is formed then second equivalence at D

106
Asish Mahapatra ·

nicely explained...

i was thinking all the time it was monobasic acid....

29
govind ·

yes agree with Asish volume correction shud be neglected wen volume is very high
@Manmay we say 1 + α ≈ 1 wen α < < 1 ..so since volume is high so an2/V2 will be low and presuure is also given very less..so we cant neglect it..

106
Asish Mahapatra ·

then what should be the answer govind??

btw solved the first one?

1
Manmay kumar Mohanty ·

ya. sorry i did the opposite thing.
So by neglecting Volume correction I guess ans will be (d)

39
Pritish Chakraborty ·

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