encountered this today...

Arrange thse lewis acids in odere of strength
FeCl3
ZnCl2
SnCl2
AlCl3
BF3
H+

7 Answers

1
pranav ·

or AL cl3 and fe cl3 exchange places?

1
Avinav Prakash ·

BF3 > AlCl3 > ZnCl2 >FeCl3 > SnCl2

29
govind ·

@Avinav..where is H+ in ur answer...and btw BF3 should not be the strongest Lewis Acid..in BF3 there is back bonding...

1
Ankur ·

considering what govind told about back-bonding in BF3 and taking the fact about dimerisation of AlCl3. They shouldn't be much stronger lewis-acids. But both these should be more acidic then SnCl2 and ZnCl2 because of charge distribution on central atom. Moreover, since in stephens reaction SnCl2 is widely used, even it should be not much stronger lewis acid. Therefore, condition should be like:
FeCl3 > AlCl3 > BF3 > SnCl2 > ZnCl2 .

PS: I'm not sure of this way.
PPS: Do tell the right answer anyway.

4
UTTARA ·

I go with this ans

H+

BF3

Alcl 3

Fecl 3

ZnCl2

SnCl2

4
UTTARA ·

The reason is

http://pubs.acs.org/doi/abs/10.1021/ja00165a023

24
eureka123 ·

i dont have ans guys............so cant confirm anything[2]

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