guys pls solve fast exam tomorrow. morning

1-3 dibromopropane ---->(Zn + Δ) A ------> (HBr) B ------> (alc. KOH) C ----------> (Br2) D ---------> (alc. KOH/NaNH2) E

identify A,B,C,D,E

31 Answers

106
Asish Mahapatra ·

guyz plz try the conversions

11
rkrish ·

I think ans is D.

cyclopropane(3 membered ring) is more strained(Baeyer strain theory) than cyclobutane(4 membered).

1
voldy ·

the last one is your bicyclic compound . not the other one .
b/w one Q

St.A : cyclopropane is formed more easily than cyclobutane
StB : the energy of activation for formation of cyclobutane is more

1
sriraghav ·

1
sriraghav ·

wurtz reaction....

1
sriraghav ·

√

106
Asish Mahapatra ·

plz try the last one

1
big looser ......... ·

but 3 membered ring is difficult to form

106
Asish Mahapatra ·

ok..
another one...
1-bromo, 3-chloro cyclobutane --->(Na/ether) ?

11
rkrish ·

For any terminal alkyne

R--C ≡ CH ---NaNH2----> R--C ≡ C - --- + R' + (from R'Br )----> R--C ≡ C--R'

106
Asish Mahapatra ·

this one ill ask for mechanism

11
rkrish ·

HC ≡ CH -----NaNH2 + CH3Br-----> HC ≡ C--CH3

106
Asish Mahapatra ·

thx krish

do that 2nd one pls

11
rkrish ·

CH3--CH2--CH2--OH + H2SO4(conc.) ---> CH3--CH=CH2

----NBS----> CH2(Br)--CH=CH2 ---aq.KOH or noist Ag2O----> CH2(OH)--CH=CH2

106
Asish Mahapatra ·

thx bhaiyya now understood... :)

62
Lokesh Verma ·

check the images above!

1
voldy ·

cyclopropane , bromopropane , propene , 1,2dibromopropane , propyne

11
rkrish ·

If 2 moles are not mentiond , then there are 2 diff. alkenes possible .

11
rkrish ·

In 1st Q.

2 moles of acetaldehyde shud be mentiond.
So final pdt has 7 C's (conjugated diene)

2nd is also a conj.diene.

1
kamalendu ghosh ·

ok... I got u.....cheers!

11
rkrish ·

dats wat i meant....some typo....(edited)

11
rkrish ·

bhaiyya......

no. of C's in 1st ans are 1 less.[1]Also H missing(But its understood).

1
kamalendu ghosh ·

er....rkrish I think u r wrong,,,,the Br shud b at the 3rd carbon....(allyl)

11
rkrish ·

NBS reaction proceeds via free radical.

| |
--c=c--c-- + NBS ---> -c=c-- c --
| |
Br

62
Lokesh Verma ·

name the alkene which on reductive ozonlysis gives the following products:
(i) acetaldehyde + 2-oxo propanal
(ii) acetone + glyoxal + formaldehyde

1)

2)

106
Asish Mahapatra ·

convert
(i) propyl alcohol to allyl alcohol (CH2=CH-CH2-OH)
(ii) ethyne to propyne

106
Asish Mahapatra ·

name the alkene which on reductive ozonlysis gives the following products:
(i) acetaldehyde + 2-oxo propanal
(ii) acetone + glyoxal + formaldehyde

106
Asish Mahapatra ·

one more ...
how are reactions of NBS (mechanism)

1
voldy ·

formation of cyclohexane might be there but in less amount

1
voldy ·

see the important part to notice here is that the reaction is kinetically controlled and not thermodynamically .

the formation of cyclohexane is thermodynamically preferred but the afifinity for Br for Zn is high hence it abstracts th Br nearby and leaves as ZnBr2 .

hence cyclopropane is formed

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