iodoform

why 3,3dimethylbutan2one does not give iodoform test?

23 Answers

11
Sunil Kumar ·

Have a look.

11
Sunil Kumar ·

bas ravi tune kar diya mazak faaltu main.......
joke mat maar jawab de........

1
Ravikant Mishra ·

what is iodoform test????

1
Ravikant Mishra ·

the compound is very stable there fore it doesn't give the iodoform test

11
Sunil Kumar ·

Ok...

1
vector ·

i ve just posted 4 or 5 que try them

11
Sunil Kumar ·

I didn't said U r wrong.
I just wanted to show that there is enolate ion formation in the mechanism....

1
vector ·

that s wat i had posted

11
Sunil Kumar ·

For the question u gave i'm not much convinced by the fact that due to enol formation poses a problem for reaction cause enolate ion are always in equilibrium with keto group and their concentration is larger in solution only when there is β diketones or any carbonyl compound in which there is resonance stabilisation or intramolecular H-bonding.

So I also think the main factor should be Stearic hindrance.....

1
vector ·

but do u think it has sum thing to do wid rate n feasiblity of rxn

11
Sunil Kumar ·

There is a transition of Carbonyl group and the enolate ion at every stage....

So the red boxes compounds in the diagram are always in equilibrium with enolate ion.
So u can't deny the fact that there is enolate ion in the reaction.

1
vector ·

why u made d enolate ion it s doing nothing in rxn

1
rahul wadhwani ·

when enol intermediate form it favours in more substituted alkene & steric effect

1
vector ·

YA POST IT N ALSO SEE MY 2 Q ON ELIMINATION I JUST POSTED

1
big looser ......... ·

post

11
Sunil Kumar ·

I agree with rahul and there is enol formation during Iodoform reaction.
If u require i can post the whole mechanism.......

1
vector ·

@may be for iit
dn w at acc to r u is d reason

1
big looser ......... ·

here steric crowding will have no effect on reaction

1
vector ·

even i think so rahul u confirm d thing there is no enol formation
however i support u in stearic crowding reason
tell me if i m wroong

1
big looser ......... ·

i know the mechanism but there is no formation of enol

1
rahul wadhwani ·

have u read it mechanism in it enol is formed

1
big looser ......... ·

why ?????????????????????????? rahul i didn't get your point

1
vector ·

ok thanks

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