organic prob....

An organic cmp A which is used in d manufacture of dioxan on oxidation wit powerful oxidisin agent gives cmp B .. A on oxidation wit dil.nitric acid to give C...
IDENTIFY A,B,C.....

12 Answers

13
Двҥїяuρ now in medical c ·

A------>CH2OH-CH2OH

B------>COOH-COOH
C------>COOH-COOH
B---->CO2......may be

1
Pavithra Ramamoorthy ·

B n C????????

13
Двҥїяuρ now in medical c ·

i m not sure abt what glycol gives on oxdn with nitric acid......

1
Pavithra Ramamoorthy ·

B IS WRON.....

13
Двҥїяuρ now in medical c ·

is B CO2[7]

then i think C may be COOH-COOH

because

CH2OH-CH2OH -----Oxdn(with HNO3)---->COOH-COOH

COOH-COOH ----drastic oxdn----->CO2+H2O

1
Pavithra Ramamoorthy ·

no dude.... B is not co2

13
Двҥїяuρ now in medical c ·

hey...dude..plz tell the ans

or tell the oxidizing agent...i mean.... how powerful is it.....

1
Pavithra Ramamoorthy ·

oxidisin agent... acidified K2Cr2O7

1
Pavithra Ramamoorthy ·

oxidisin agent... acidified K2Cr2O7

13
Двҥїяuρ now in medical c ·

as far as i know acidified K2Cr2O7 gives oxalic acid...which then gives CO2

if the ans is HCHO...then oxidizing agent is HIO4....it then gives HCOOH

plz tell me what the ans is.....

1
Pavithra Ramamoorthy ·

FORMIC ACID (HCOOH).................

13
Двҥїяuρ now in medical c ·

then i think they considered HIO4 as oxdn agent it gives HCOOH

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