RTPF Assertion Reason

BITSAT 2015 Sample Questions › Organic Chemistry questions › RTPF Assertion Reason

S1 : A mixture of primary,secondary and tertiary amines is formed in good yield by heating carbonyl compounds with NH₃ and H₂ in presence of a catalyst.

S2 : The eqb. constant for addition of NH₃ to all carbonyl compounds are very high.

IS S1 correct ?? "Good yield" is obtained ??

#Chemistry #Organic Chemistry

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4 Answers

39

Pritish Chakraborty ·2010-04-03 02:53:13

Good yield is obtained only when excess of ammonia is used...so with normal quantities of ammonia we do not get a good yield. I think S1 might be false and S2 is true.

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Gone.. ·2010-04-03 02:56:37

I thought so..

Ans given C..(S1 true,,S2 false)

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39

Pritish Chakraborty ·2010-04-03 02:57:50

lola...I don't remember ammonolysis of carbonyls. Have to read it again.

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Gone.. ·2010-04-03 02:59:59

[1]

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