tollen test

do aromatic alcohals n alpha hydroxy ketones give tollen test?

26 Answers

11
Mani Pal Singh ·

K

1
vector ·

sum more views reqd:)

13
Двҥїяuρ now in medical c ·

good Q...thatz y fructose gives +ve test....

39
Dr.House ·

i think its because of the M and I effects shown by the -OH when placed at ortho meta and para position, i dont have any other idea.

1
vector ·

sry edited:)

39
Dr.House ·

wat? hydraquinone is giving or not giving?

1
vector ·

actually catechol n resorcinol do not give d test n hydroquinone is giving test cud u explain

39
Dr.House ·

the answewr lies in the question u asked. if aromatic alcohols are oxidisable, then this will also be oxidisable. as u know it is a aromatic di-ol na.

1
vector ·

is hydroquinone easily oxidisable

39
Dr.House ·

ab , mujhe jo pata tha batha diya, aage i will have to see if the compound is easily oxidisable etc etc.

1
vector ·

do hydroquinone gives d test?

11
Mani Pal Singh ·

COOL

39
Dr.House ·

@akand, u only try, the clue i can give is that C2-C23 centre is very easily prone for oxidation

@manipal: i donno from where i read it, its been long i stopped organic. i think it was given by our sir.

11
Mani Pal Singh ·

alcohals,ketones---->tollen test
maine pehle kabhie bhi nahi suna
jahan tak mujhe pata hai it is given by aldehydes only

62
Lokesh Verma ·

@manipal.. there is no need to think for a source here.

think in terms of the process.. the alpha hydrogen is available for exchange..

1
Akand ·

wel try for CH3CH(OH)COCH3.......WATS D PRODUCT??

39
Dr.House ·

dude, woh tho depends na........

i cant definitely say just alcohol will get oxidised to ketone, and actually it depends, but

watever information i gave, its right, i am damn sure

1
Akand ·

wel mathi..........phenol doesnt giv i think..........

1
vector ·

@mathie thanks for d information

1
Akand ·

but mathi.........then wat wud d product be????

39
Dr.House ·

aromatic alocohols, let me have a look

39
Dr.House ·

in your question, aplha hydroxy ketones gice it because

two adjacent carbons, one containing carbonyl and other contains alcohol. this is very easiiily prone to oxidation.

1
Akand ·

wel i dont think so........... i dunno about d second one but 1st one definitely no...

39
Dr.House ·

the following give tollen`s test, kindly remember if u can

1formic acid
2all formates
3alpha keto carboxilic acids
4alpha hydroxy carboxylic acids
5alpha hydroxy ketones

11
Mani Pal Singh ·

PLEASE CONSULT NCERT IF ANY DOUBTS

1
vector ·

i read it sumwhr n was confused

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