CHEMICAL KINETICS

A 1st order reacn with half life 20 days is cccuring at 27°C . If 10-2 % molecules r in activated state . Find the maximum rate constant.

(A) 3.4 * 10-2

(B) 3.4 * 102

(C) 10-4

(D) can't be determined

3 Answers

1
Euclid ·

ans (B)

Maximum value of rate constant = A (Arrhenius Factor)

also fraction of molecules in activated state = kA = 10-2100

so A = 693/2 ≈ 3.4 * 102

6
AKHIL ·

ok
thnx euclid
:)

6
AKHIL ·

now if the above reacn.( R-> P) wud hav taken place in this manner ( R-> 3P) , what shud be the half life of the reacn.?

(A) 20 days

(B) 48.18 days

(C) 6.2 * 10-3 days

(D) 60 days

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