Ionic equilibrium

What is total volume of solution(in ml) when 1M NaOH is required to be added in 100mL 1M CH3COOH(Ka=10-5) solution so that pH is 6.

4 Answers

1
aieeee ·

Here , its reaction between a strong acid and a weak base.
so,use pH = pKa + log [salt]/[acid]

here, [salt] cn be found out in M. it would perhaps come 10M.
now, volume of the acid and its molarity is known,along with base's molarity.
so,use: M1V1=M2V2

volume of base = 0.1 L.

1
champ ·

I got the same answer as your
but given answer is 190 ml
:-(

1357
Manish Shankar ·

let the volume of base added is V ml

mmol of salt formed=V
mmol of acid remined=100-V

we have [salt]/[acid]=10
V/(100-V)=10

or V=1000/11

total volume=V+100=2100/11 ml

1
aieeee ·

champ, here i found out the vol. of base = 0.1 L
So, total vol. of solution = 200 ml.

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