joule thomson effect

may this help http://en.wikipedia.org/wiki/Joule%E2%80%93Thomson_effect

In thermodynamics, the Joule–Thomson effect or Joule–Kelvin effect or Kelvin–Joule effect describes the temperature change of a gas or liquid when it is forced through a valve or porous plug while kept insulated so that no heat is exchanged with the environment.

in it As a gas expands, the average distance between molecules grows. Because of intermolecular attractive forces (see Van der Waals force), expansion causes an increase in the potential energy of the gas. If no external work is extracted in the process and no heat is transferred, the total energy of the gas remains the same because of the conservation of energy. The increase in potential energy thus implies a decrease in kinetic energy and therefore in temperature.

but in ideal gase there is no intermolecular forces so.....[1][1][1][1][1]