pls help m tensed

[2] [2] pls help
yaar mujhe chemical equillibrium main dikkat aarahi hai pls help karo badi basic doubts aarahi hai .....
jaise yeh question hai
3g mole of pcl5 is heated in a flask of 4ltrs at equillib it dissociates to pcl3 and cl2 degree of dissociation is 40% calc equllibrium constant ...
isme ek baat btao
pcl5 ==> pcl3 + cl2
a(1-x) ax ax
a= 3 x = 0.4 v = 4
yaar mujhe yeh step nahi samaj aaya hum yeh line kaise likhte hai ?????

16 Answers

11
virang1 Jhaveri ·

3g moles wats dat?
3g is the mass or is it 3 moles?

1
spiderman ·

mujhe bhi nahi samaj aaya op tondon ka question hai [2]

1
spiderman ·

usse important can u explain me yeh line likhte kaise hai mai bhul gaya [2]

11
Mani Pal Singh ·

mushkil aggar 4 mein hai to
woh to aata hi hai
dont u remember that the next step after ur words is that divide both RHS and LHS by 4
U HAVE TO CONSIDER THE VOLUME TO FIND K

11
virang1 Jhaveri ·

they have assumed the intial mass as a

1
spiderman ·

yaar manipal pls mujhe pehli waali line samjha de yeh waali line likhte kaise hai ???
yaar mujhe pehle pls wo line btao ! plsss

106
Asish Mahapatra ·

see degree of dissociation is 40%

==> ki out of the reactants.. 40% of it will dissociate at equilibrium i.e. take part in the reaction.

So. u can do this is two ways.

initially there are 3 mo0les of reactants out of which 40% dissociates ..
So, at equilibrium moles of reactants = 0.6*3 = 1.8
Now. 1 mole of PCl5 gives one mole each of PCl3 and Cl2.

So. moles of PCl3 = molesof Cl2 = moles of PCl5 that reacted = 0.4*3 = 1.2

Second method is wat u have mentioned..

Out of one mol.. 0.4 mol dissociates as deg of dissociation = 40%..

Now suppose there are a moles of reactants. Then moles of reactants dissociated = a.x

Moles of reactants remaining = a-ax = a(1-x)
Now. moles of reactant dissociated = moles of PCl3 = moles of Cl2 = ax ..

Suppose it was 2Cl2 then 1 mole of reactant wud give 2 moles of Cl2.. then it wud have been 2ax.

In this problem.. so, the equilibrium constant = written in my next to next post

1
ANKIT MAHATO ·

isme ek baat btao
pcl5 ==> pcl3 + cl2
a(1-x) ax ax
a= 3 x = 0.4 v = 4

yaar it is given that 40 % is dissociated that means that 60 % is left a(1- 40/100) = .6 a .. yeah to clear hoga
ab yeh dekho 1 PCl5 on dissociation gives 1 PCl3 and 1 Cl2 so ax PCl5 that is 40a/100 PCl5 gives 40a/100 PCl3 and 40a/100 Cl2 and hence
the K = [ PCl3][Cl2]/[ PCl5] = [.4a/V][.4a/V]/[.6a/V] = .12/.18 = 2/3

106
Asish Mahapatra ·

3 gram moleculs means 3 moles

11
virang1 Jhaveri ·

Asish equilibrium constant takes consideration of molar concentration and not moles. = 0.2

1
ANKIT MAHATO ·

3 gram molecules 3 mole hota hai .. 3 gram moles kuch nahi hota hai

106
Asish Mahapatra ·

sry the equilibrium const wud be (1.2/4)*(1.2/4)/(1.8/4) = 0.2

11
virang1 Jhaveri ·

therefore equilibrium constant is 0.2

1
spiderman ·

haan 0 .2 hi hai
@ankit jo book main tha maine wahi likha ... mujhe bhi palle nahi par raha tha ...

1
spiderman ·

thanks asish and virang

1
ANKIT MAHATO ·

yup mera answer wrong hai sorry for misleading ... [156]
wrong calculation

Your Answer

Close [X]